几何位相非线性变化的实验研究

本文报道了Pancharatnam位相非线性变化的实验研究，实验结果与理论预言符合得很好。Pancharatnam位相的这种非线性可能在光开关中得到应用。     

钾钠铌酸锶钡系列晶体自泵浦位相共轭镜的研究

报道了钾钠铌酸锶（ＫＮＳＢＮ）晶体系列自泵浦位相共轭反射镜的最新研究结果。ＫＮＳＢＮ：Ｃｕ、ＫＮＳＢＮ：Ｃｏ和ＫＮＳＢＮ：Ｃｅ自泵浦位相共轭反射镜的反射率分别可达７３％、７３％和８４．３％，ＫＮＳＢＮ：Ｃｕ自泵浦位相共轭反射镜的响应时间在低功率下达２００ｍｓ。     

Effect of Bi and Sr concentrations on the formation of the 2223 phase in Bi-Pb-Sb-Sr-Ca-Cu-O materials, obtained under different conditions of thermal treatment

The superconducting properties and the phase and chemical composition of Bi _x Pb_0.3Sb_0.1Sr _y Ca₂Cu₃O_z (x=1.5, 1.6, and 1.7;y=1.9, 2.0, and 2.1) materials synthesized by one-step and multistep thermal treatments have been investigated. The multistep annealing between 825–875°C promotes the 2223 phase. The change of Bi concentration has little effect on the 2223 phase formation, regardless of the kind of thermal treatment used, but increasing the Sr concentration (y> 2) strongly inhibits this phase. It has also been established that the loss of Pb after synthesis depends on the initial Bi concentration. The loss of Pb decreases when the initial Bi content is lower.     

α-戊(己)基肉桂醛的合成

采用聚乙二醇 ( PEG 2 0 0 )作相转移催化剂 ,用氢氧化钾醇水溶液代替氢氧化钾醇溶液合成了 α 戊 (己 )基肉桂醛 ,收率提高到 85%以上。用此工艺合成的产品纯度高 ,香气好 ,具有较高的工业实用价值。     

相转移催化合成芳基烷基醚

报道了以四丁基溴化铵为相转移催化剂，简便地合成了１０个芳基烷基醚，反应几乎是定量地快速进行。     

热力学相图计算技术在闪速燃烧合成氮化硅铁中的应用

将热力学相图计算技术应用于Si-Fe-O-N体系,以评估由FeSi75粉闪速燃烧合成氮化硅铁的条件和目标产物。结果表明:将闪速燃烧温度控制在1200～1500℃之间较为适宜,此时平衡态产物中除主要含有Si3N4以外,还有一定量的Fe与Si间化合物和少量稳定的SiO2存在。此计算结果与实际试验结果吻合良好。     

附加励磁阻尼控制抑制次同步谐振研究

基于阻尼特性分析对抑制次同步振荡的附加励磁系统阻尼控制器（SEDC）进行了详细研究。首先基于IEEE次同步谐振第一标准测试系统及IEEE ST1A型励磁系统设计相应的SEDC。采用测试信号法，通过计算发电机组的次同步电气阻尼特性，分析所设计的SEDC对发电机组次同步振荡的抑制效果。结果表明，SEDC在不采用带通滤波器的方式下，将转速偏差经适当移相及放大，通过对励磁电压的调节，可以提供足够的阻尼转矩抑制次同步谐振;采用带通滤波器可大大提高通带频率对应的电气阻尼，同时对多个模态采用带通滤波，可以同时提高各个扭振频率处的电气阻尼，有利于次同步谐振的抑制。     

新型微波-毫米波幅相测试系统及扩展应用

介绍了一种新型微波 毫米波幅相测试系统及其在相关测试领域中的典型应用。与传统微波幅相测试系统相比 ,该系统具有原理新颖、结构简单、扩展频段容易和使用方便等优点。本系统目前广泛应用于紧缩场电气性能检测、天线测量和RCS测量等领域中 ,频率范围为 1～ 110GHz。本测试系统已经申请国家专利 ,并通过相关部门鉴定。     

A hybrid extended finite element/level set method for modeling phase transformations

A hybrid numerical method for modelling the evolution of sharp phase interfaces on fixed grids is presented. We focus attention on two‐dimensional solidification problems, where the temperature field evolves according to classical heat conduction in two subdomains separated by a moving freezing front. The enrichment strategies of the eXtended Finite Element Method (X‐FEM) are employed to represent the jump in the temperature gradient that governs the velocity of the phase boundary. A new approach with the X‐FEM is suggested for this class of problems whereby the partition of unity is constructed with C¹(Ω) polynomials and enriched with a C⁰(Ω) function. This approach leads to jumps in temperature gradient occurring only at the phase boundary, and is shown to significantly improve estimates for the front velocity. Temporal derivatives of the temperature field in the vicinity of the phase front are obtained with a projection that employs discontinuous enrichment. In conjunction with a finer finite difference grid, the Level Set method is used to represent the evolution of the phase interface. An iterative procedure is adopted to satisfy the constraints on the temperature field on the phase boundary. The robustness and utility of the method is demonstrated with several benchmark problems of phase transformation. Copyright © 2002 John Wiley & Sons, Ltd.     

Oxidation of porous nanocrystalline titanium nitride. II. Scale structure and composition

We have used x-ray phase analysis to study the composition of the products of reaction between oxygen and nanocrystalline powders with particle sizes 15, 40, 55, and 80 nm, and also specimens pressed (and sintered) from them. The powders were oxidized in air at 100°C (400 h) to 500°C (5 min), while the sintered specimens were oxidized at 600–900°C for 15, 120, and 240 min. In all cases, in the initial oxidation step the oxynitride Ti(O_xN_y) is formed, which over time is oxidized to TiO, Ti₂O₃, Ti₃O₅, TiO₂ (anatase) and TiO₂ (rutile). In the range 600–800°C, formation of a continuous oxide layer and conversion of anatase to rutile slows down diffusion of oxygen in the scale. We have established that at 900°C, the growth rate of the scale thickness increases and so the reflections from the oxynitride are barely noticeable on the diffraction patterns taken from the surface of the oxidized specimen. In these diffraction patterns, along with strong reflections from the rutile, we also observed weak reflections from lower oxides and anatase, which may be due to reaction between oxygen and the titanium ions diffused to the scale surface. We have concluded that at T > 850°C, the mechanism for oxidation of TiN changes. This is due to superposition of counterdiffusion of titanium ions on the diffusion of oxygen. __________ Translated from Poroshkovaya Metallurgiya, Nos. 3–4(448), pp. 72–78, March–April, 2006.